Re the Fifth Gear feature it is turbocharged cars that as standard make the biggest gains using V-Power, normally aspirated cars don't benefit from quite such a dramatic gain.
It does take the ECU a while to adjust to the new fuel and although you usually feel a difference quite quickly but it takes a bit of running to fully adjust, so if you want to get the maximum out of a better fuel say on a track day you want to fill the car up a couple of times in advance to get the full benefit.
We get the same effect in racing, we have been testing over the winter using Super Unleaded pump fuel but with the season starting over Easter this week we switched the cars to 102 race fuel to ensure they are flushed through and the ECU's adjust prior to the first races.
My tuned Impreza road car runs best on either Shell V-Power or Tesco 99, it is mapped specifically for SUL and there is a noticeable drop off with other brands of SUL.
HTH
Robin